(A) Molecular structures of receptors 29–32.
(B) Single crystal X-ray structure of the complex [Cl2]2− ⊂ 30.
(C) Single crystal X-ray structure of the complex [Cl2]2− ⊂ 31.
(D) Single crystal X-ray structure of the complex [Cl2]2− ⊂ 32.
All anions encapsulated within the cavities are shown in space-filling form. Inter-halide distances: (B) 3.62 Å, (C) 3.83 Å and (D) 4.03 Å. Color code: C = gray, N = blue, O = red, Cl = green. The counter cations and solvent molecules outside the cavities are omitted for clarity.