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. 2017 Dec 22;9(6):1510–1520. doi: 10.1039/c7sc04353h

Table 1. The polymorphs of TA and INA.

Compound Form Synthon Space group Stability Crystallization solvent
TA α Carboxyl dimer P1 Metastable at RT Chloroform
β Carboxyl catemer P21 Stable at RT Ethanol
INA I Amide catemer P21/c Metastable at RT Nitromethane
II Amide dimer P21/c Stable at RT Ethanol, methanol, 2-propanol
III Amide catemer Pbca Metastable at RT N/A
IV Amide catemer Pc Metastable at RT Nitrobenzene
V Amide catemer P21/c Metastable at RT N/A