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. 2018 Mar 2;140(13):4580–4587. doi: 10.1021/jacs.7b13624

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Copyright © 2018 American Chemical Society

This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License, which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.

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CO adsorption on CeO₂ supported Pd₈ and Pd₈O_x nanoparticles. (a) A linear scaling relationship between the reaction barriers of lattice oxygen vacancy formation and CO and O adsorption energies on Pd₈(O_x) and CeO₂, respectively. (b) A linear scaling relationship between CO adsorption energies and the charge state of the binding Pd atom. (e,f) Corresponding configurations for CO adsorption on Pd₈/CeO₂, Pd₈/CeO_2–x′, Pd₈O₁₂/CeO₂, and Pd₈O₆/CeO₂ structures, respectively.