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(A) Reaction of (tBupy)2PdIIX2 species with N-methoxy-2,6- difluorobenzamide to afford (a mixture of) tBupy-ligated PdII–amidate species. (B) Distribution of PdII species observed in mixtures of (tBupy)2PdIIX2 and 2 equiv of N-methoxy-2,6-difluorobenzamide; the “O2” complex corresponds to PdII–peroxo complex 1.
