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. Author manuscript; available in PMC: 2019 Feb 2.
Published in final edited form as: ACS Catal. 2017 Dec 20;8(2):1003–1008. doi: 10.1021/acscatal.7b03688

Figure 6.

Figure 6

Stereoretentive Suzuki–Miyaura couplings of amide 39 and enantioenriched amide 41. Conditions: Ni(cod)2 (5 mol %), 10 (10 mol %), substrate (1.0 equiv), boronate 5 (2.5 equiv), K3PO4 (4.0 equiv), toluene (1.0 M), and H2O (2.0 equiv) heated at 70 °C for 2 h. Yield reflects the average of two isolation experiments. Legend: (a) reaction run at 90 °C for 2 h. Yield determined by 1H NMR analysis using hexamethylbenzene as an external standard.