Table 1.

Comparison of Properties of 2 and 3

properties	2	3
ν(Fe=O) (cm−1)	798	862
r(Fe=O) (Å)	1.64	1.59
XAS pre-edge area units	52	65
E0′(V vs NHE)	0.44 (pH 12)	1.19 (pH 7)
k2 (BnOH) @ RT	0.08(1) M−1 s−1	220(20) M−1 s−1
KIE (BnOH oxidation)	∼3	∼12
ΔH‡ (kcal/mol)	10.7 ± 0.7	7.9 ± 0.5
ΔS‡ (cal/mol/K)	−27 ± 2	−23 ± 2
TΔS‡ (kcal/mol)	−8.1 ± 0.6	−6.9 ± 0.6
ΔG‡ (kcal/mol)	19 ± 1.2	15 ± 1