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. 2018 Mar 19;10(15):13158–13180. doi: 10.1021/acsami.8b00183

Table 3. GPC (Film Thickness per Cycle and Number of Atoms Deposited per nm2 per Cycle) and Elemental Composition of Titanium Nitride Films Deposited at 200 °C with and without Average Bias Voltages, ⟨Vbias⟩, Applied during the Ar + H2 Plasma Exposure Stepa.

    RBS
ERD
Vbias GPC GPC [Ti] (# Ti at. per GPC [N] (# N at. per GPC [O] (# O at. per   [O] [C] [Ar] [H]
(V) (Å/cycle) nm2 per cycle) nm2 per cycle) nm2 per cycle) N/Ti at. % at. % at. % at. %
0 0.47 ± 0.02 1.22 ± 0.03 0.76 ± 0.10 0.92 ± 0.05 0.63 ± 0.06 28 ± 5 <d.l.b 0 ± 0.06 10 ± 7
–130 0.35 1.46 ± 0.01 1.18 ± 0.04 0.10 ± 0.02 0.80 ± 0.02 3 ± 2 <d.l. 0.20 ± 0.05 3 ± 3
–255 0.34 1.18 1.17 0.06 1.0 2 12 ± 3 0.77 2
a

Typical uncertainties are given in the first and second rows unless otherwise stated.

b

Values below detection limit (d.l.) of 8 at. % for [C].