Fig. 5. Mechanochemical formation of a pillared MOF material. Starting from ZnO, terephthalic acid, and dabco (1,4-diazabicyclo[2.2.2]octane),50 the formation of a fleeting short-lived intermediate (X-ray reflection at 0.5° in 2theta) around 4 minutes of milling can be observed in the temperature profile as an interruption in the heating profile.
