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. 2018 Apr 18;6:100. doi: 10.3389/fchem.2018.00100

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Copyright © 2018 Schilling and Luber.

This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

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Free energy profile of the O−O bond formation catalyzed by [Co^II(Py₅)(OH₂)]²⁺. Note the associative mechanism where the nucleophile first coordinates to the cobalt center. Crandell et al. (2015), Copyright Wiley-VCH Verlag GmbH & Co. KGaA. Reproduced with permission.