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a) Formation of mouldable self‐healing scaffolds from supramolecular assembled microbeads. b) Supramolecular assembly between cucurbit[8]uril‐threaded highly branched polyrotaxanes (HBPCB[8]) and naphthyl‐functionalised hydroxyethyl cellulose (HEC‐Np). c) Photographs of the mouldable transition from a microbead suspension to a macroscale scaffold upon thermal treatment.
