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Hydrogenation of 2,3-dimethylbut-1-ene with the C8 PdNP catalysta
| Time |
|
|
|
|---|---|---|---|
|
|
|
|
|
| Terminal alkene (%) | Internal alkene (%) | Alkane (%) | |
| 1 h | 88% | 12% | 0% |
| 3 h | 78% | 22% | 0% |
| 6 h | 66% | 34% | 0% |
| 24 h | 48% | 52% | 0% |
Reaction conditions: 0.5 mmol diene, 5 mol% Pd catalyst, 2.5 mL CDCl3, 1 atm H2, 24 h reaction. Yields were obtained by 400 MHz 1H NMR.
