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. Author manuscript; available in PMC: 2019 Mar 14.
Published in final edited form as: Chem Rev. 2018 Feb 5;118(5):2554–2592. doi: 10.1021/acs.chemrev.7b00457

Figure 5.

Figure 5

Simplified diagram for resonance Raman data collection of peroxodiferric intermediates. The absorption spectrum is of oxyHr (prepared by Dr. Anna Komor) with a peroxo-to–FeIII LMCT transition at ∼500 nm, marked by the vertical dashed line. Excitation by a laser with similar wavelength (green curved line) into the LMCT band results in the observation of resonance enhanced vibrations, such as the O–O stretch at 844 cm−1.