Table 1.
No. | 1 | 2 | ||
---|---|---|---|---|
δC | δH | δC | δH | |
1 | 40.2 (CH) | 3.10 ddd (3.4, 8.3, 11.7) | 39.1 (CH) | 3.12 ddd (2.8, 8.3, 11.7) |
2 | 77.6 (CH) | 5.53 dd (8.3, 11.0) | 77.1 (CH) | 5.48 dd (8.3, 11.0) |
3 | 119.8 (CH) | 4.90 d (11.0) | 120.0 (CH) | 5.00 d (11.0) |
4 | 143.8 (C) | 142.4 (C) | ||
5 | 39.6 (CH2) | 2.16 m | 43.1 (CH2) | 2.78 m |
1.80 dt (4.8, 12.4) | 2.76 m | |||
6 | 24.2 (CH2) | 2.39 m | 128.6 (CH) | 5.80 td (8.3, 15.8) |
2.03 m | ||||
7 | 125.6 (CH) | 4.70 br d (8.9) | 136.4 (CH) | 5.46 d (15.8) |
8 | 133.2 (C) | 84.4 (C) | ||
9 | 39.5 (CH2) | 2.31 br d (13.8) | 37.7 (CH2) | 1.77 m |
2.14 m | 1.72 m | |||
10 | 22.9 (CH2) | 2.14 m | 22.5 (CH2) | 2.36 m |
2.00 m | 1.96 m | |||
11 | 129.8 (CH) | 5.23 dd (5.5, 9.6) | 130.5 (C) | 5.31 dd (4.1, 10.3) |
12 | 132.0 (C) | 131.9 (C) | ||
13 | 77.3 (CH) | 5.04 d (11.0) | 76.8 (CH) | 5.00 d (11.7) |
14 | 32.4 (CH2) | 2.41 m | 32.6 (CH2) | 2.20 ddd (2.8, 11.7, 14.4) |
1.54 m | 1.52 dd (11.7, 14.4) | |||
15 | 138.3 (C) | 138.1 (C) | ||
16 | 170.3 (C) | 170.2 (C) | ||
17 | 120.2 (CH2) | 6.25 d (3.4) | 120.9 (CH2) | 6.28 d (3.4) |
5.49 d (3.4) | 5.52 d (3.4) | |||
18 | 15.1 (CH3) | 1.75 s | 16.1 (CH3) | 1.91 s |
19 | 15.2 (CH3) | 1.58 s | 20.7 (CH3) | 1.42 s |
20 | 10.2 (CH3) | 1.60 s | 10.2 (CH3) | 1.61 s |
13-OAc | 170.9 (C) | 170.9 (C) | ||
21.2 (CH3) | 2.05 s | 21.2 (CH3) | 2.05 s |