Scheme 3.
Bis(monothiolates) Fe2(SR)2(CO)2(dppv)2 Are More Rigid Stereochemically (Top) than the Related Chelating Dithiolates Fe2[(SCH2)2X](CO)2(dppv)2, Which Undergo Degenerate Racemizationa
aPh groups on phosphorus omitted for clarity.
Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.