Table 3.

Acceptorless dehydrogenation by Pd@SiCN^a

^a Reaction conditions: 50 mg (0.18 mol% active metal) Pd@SiCN, 1.0 mmol substrate, 0.75 mL diglyme, 180–200 °C, 18 h (under slight argon flow)

^b Yields of isolated products