Table 1.
Type of lignin | Kraft | Lignosulfonate | Soda | Organosolv | References |
---|---|---|---|---|---|
Structure | [80] | ||||
Separation methods | Precipitation (pH change)–ultrafiltration | Ultrafiltration | Precipitation (pH change)–ultrafiltration | Precipitation (addition of non-solvent) Dissolved air flotation |
[80] |
Active extracting agent | NaOH, Na2S | H+ , HSO3− | NaOH | 40–60 wt% aqueous ethanol | [26, 111] |
pH of isolation medium | 13–14 | 1–2 (acid bisulfite) 3–5 (bisulfite) |
13–14 | – | [26, 111] |
Temp. (°C) | 155–175 | 125–145 (acid bisulfite) 150–170 (bisulfite) |
155–175 | 180–210 | [26, 111] |
Sulphur (%) | 1.0–3.0 | 3.5–8.0 | 0 | 0 | [80] |
Nitrogen (%) | 0.05 | 0.02 | 0.2–1.0 | 0–0.3 | [80] |
Molecular weight (× 103 g mol−1) | 1.5–5 (up to 25) | 1–50 (up to 150) | 0.8–3 (up to 15) | 0.5–5 | [80] |
Solubility | Alkali and some organic solvents | Water | Alkali | Broad range of organic solvents | [80] |
Tg (°C) | 140–150 | 130 | 140 | 90–110 | [80] |
Td (°C) | 340–370 | 250–260 | 360–370 | 390–400 | [80] |
Scale (ktpa) | 60 | 1000 | 5–10 | ∼ 3 | [112] |