Table 1.
The calculated lattice parameters (a, b, c, α, β, and γ), unit cell volumes, and average crystallite sizes of the (La0.6Pr0.4)0.67Ca0.33MnO3 nanoparticles post-annealed at (A) 700 °C, (B) 800 °C, (C) 900 °C, and (D) 1000 °C for 5 h. Lattice parameters within ± 0.0003(a, b, c) are calculated from the XRD data. Average crystallite sizes within ± 1 are calculated using the Scherrer’s equation
| Sample number | Annealing temperature (°C) | Lattice parameters (Å) | Unit cell volume (Å3) | Average crystallite size (nm) |
|---|---|---|---|---|
| A | 700 |
a = 5.4365, b = 7.6727, c = 5.4334 α = β = γ = 90o |
226.64 | 21 |
| B | 800 |
a = 5.4411, b = 7.6940, c = 5.4213 α = β = γ = 90o |
226.96 | 32 |
| C | 900 |
a = 5.4429, b = 7.6887, c = 5.4470 α = β = γ = 90o |
227.95 | 40 |
| D | 1000 |
a = 5.4446, b = 7.6960, c = 5.4441 α = β = γ = 90o |
228.12 | 47 |