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. 2017 Oct 30;50(21):8658–8669. doi: 10.1021/acs.macromol.7b01752

Table 1. Molecular Parameters of the Polystyrene-Tethered Silica Particlesa.

  grafting characteristics
particles films  
sample σ (nm–2) N h* (nm) h# (nm) ϕPS
DP1300 0.53 1300 59 ± 4 63 ± 8 0.86 ± 0.04
DP2480 0.39 2480 83 ± 7 87 ± 12 0.93 ± 0.03
DP530 0.27 530 18 ± 6 19 ± 3 0.56 ± 0.02
DP1170 0.08 1170 15 ± 4 11 ± 6 0.50 ± 0.02
a

h*: brush height determined by SEM images in Figure S1; h#: brush height determined by TEM images in Figure S6; ϕPS: volume fraction of PS is determined by different methods (see Table S1).