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. 2018 Mar 27;9(16):3964–3969. doi: 10.1039/c8sc01154k

Table 2. Substrate scope a , b .

graphic file with name c8sc01154k-u2.jpg

aReaction conditions: o-carboranyl methylamines (0.1 mmol), Ar–I (3.0 equiv., 0.3 mmol), Pd(OAc)2 (10 mol%, 0.01 mmol), glyoxylic acid monohydrate (L6, 20 mol%, 0.02 mmol), AgTFA (3.0 equiv., 0.3 mmol), AcOH (3.0 equiv., 0.3 mmol), H2O (3.0 equiv., 0.3 mmol), HFIP (0.2 M, 0.5 mL), 80 °C, N2 atmosphere, 12 h.

bIsolated yield.

cIsolated without treatment with Na2CO3 in THF/H2O.