Table 2. Substrate scope a , b .
aReaction conditions: o-carboranyl methylamines (0.1 mmol), Ar–I (3.0 equiv., 0.3 mmol), Pd(OAc)2 (10 mol%, 0.01 mmol), glyoxylic acid monohydrate (L6, 20 mol%, 0.02 mmol), AgTFA (3.0 equiv., 0.3 mmol), AcOH (3.0 equiv., 0.3 mmol), H2O (3.0 equiv., 0.3 mmol), HFIP (0.2 M, 0.5 mL), 80 °C, N2 atmosphere, 12 h.
bIsolated yield.
cIsolated without treatment with Na2CO3 in THF/H2O.