Table 1.

Kinetic equations for TCE degradation in different oxidation systems

System	Reaction Period	Temperature (°C)	Regression equation	R2	kobs a (h−1)
SO b	Rapid-stage	10	y = −0.076x + 0.014	0.90	0.076
SO	Rapid-stage	20	y = −0.123x − 0.016	0.95	0.123
SO	Rapid-stage	30	y = −0.208x − 0.054	0.83	0.208
SO	Rapid-stage	40	y = −0.362x − 0.089	0.85	0.362
SO	Rapid-stage	50	y = −0.533x − 0.087	0.93	0.533
SO	Slow-stage	10	y = −0.011x − 0.161	0.93	0.011
SO	Slow-stage	20	y = −0.018x − 0.237	0.98	0.018
SO	Slow-stage	30	y = −0.044x − 0.311	0.95	0.044
SO	Slow-stage	40	y = −0.116x − 0.420	0.99	0.116
SO	Slow-stage	50	y = −0.242x − 0.496	0.98	0.242
STO c	Entire reaction	10	y = −0.034x + 0.025	0.90	0.034
STO	Entire reaction	20	y = −0.104x + 0.014	0.94	0.104
STO	Entire reaction	30	y = −0.361x + 0.212	0.92	0.361
STO	Entire reaction	40	y = −0.899x + 0.304	0.96	0.899
STO	Entire reaction	50	y = −1.383x + 0.221	0.93	1.38

^aK_obs is the pseudo first-order rate constant

^bSO: siderite-catalyzed hydrogen peroxide oxidant

^cSTO: siderite-catalyzed binary oxidants (hydrogen peroxide and persulfate)