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. 2015 Aug 20;6(12):6847–6864. doi: 10.1039/c5sc02099a

Table 4. Lifetimes for the growth and decay of the CS state.

Dyad (solvent) Risetime (ps) Lifetime (ps) Δν of ν(CO)sym of CS state (cm–1)
[Dyad 1 pic]OTf (PrCN)34 <1 40 ± 4 –24
[Dyad 2 pic]OTf (CH2Cl2) ca. 2 42 ± 2 (and 515 ± 35) –24
[Dyad 3 pic]OTf (CH2Cl2) 8 ± 1 320 ± 15 –29