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X‐ray structure of 2 b:24 a) Showing Pd⋅⋅⋅Pd distances and encapsulated NO3 − anions along the major C2 axis, b) highlighting the Pd⋅⋅⋅Pd distances of cations orthogonal to the major C2 axis, c) a space‐filling representation of the [2]catenane with NO3 − anions removed for clarity.
