Table 1. X-ray photoemission spectroscopy derived effective thickness and packing density of TP1, TP1-up and TP1-down SAMs; X-ray absorption spectroscopy derived tilt angles; WF shifts with respect to pristine gold c .
SAM | Effective thickness (nm) | Packing density (molecules per cm2) | Tilt angle | WF shift a (eV) |
TP1 | 1.78 ± 0.04 | 4.6 × 1014 | 18 ± 3° | 0.98 |
TP1-up | 1.74 ± 0.05 | 4.2 × 1014 | 18 ± 3° | 1.41(+0.43 b ) |
TP1-down | 1.75 ± 0.05 | 4.3 × 1014 | 17 ± 3° | 0.43(–0.55 b ) |
aMeasured with a Kelvin probe; we use opposite sign conventions for Φ.
bDifference from TP1.
cExperimental values are from ref. 42.