Table 3. Summary of energy and electron transfer parameters obtained from photophysical data.
k hop (×106 s–1) | k inj (×107 s–1) | Φ RET | Φ inj | r (Å) | R hop (3D, Å) | R hop (2D, Å) | R hop (1D, Å) | |
RuDCBPY–UiO-67–TiO2 | 1.86 | 2.59 | 0.72 | 0.91 | 24 | 254 | 207 | 147 |
RuDCBPY–UiO-67–DCBPY–TiO2-OP | 3.81 | 24.5 | 0.84 | 0.98 | 19 | 177 | 145 | 102 |
RuDCBPY–UiO-67–DCBPY–TiO2-PS | 6.28 | 6.99 | 0.89 | 0.91 | 16 | 138 | 113 | 80 |
RuDCBPY–ZrMOF–TiO2 | 4.19 | 49.5 | 0.85 | 0.99 | 19 | 169 | 138 | 98 |