Table 3. Selected results for the SMC with 1·S112Y–K121E Sav on a variety of substrates ^a .

Entry	ArX	Ar′B(OH)2	Product	Temp [°C]	ee [%]	TON
1	6d	7a	8b	RT	80 (R)	32
2	6g	7e	8d	50	80 (S)	20
3	6d	7e	8e	50	74 (R)	61
4	6g	7f	8f	50	64 (S)	50
5	6g	7h	8h	RT	65 (R)	29
6	6a	7c	8b	RT	80 (R)	7
7	6b	7c	8b	RT	80 (R)	63
8	6c	7c	8b	RT	80 (R)	80
9	6f	7a	8a	RT	69 (S)	64
10	6b	7b	8a	50	76 (S)	81
11	6b	7b	8a	4	87 (S)	8 b
12	6c	7d	8c	RT	68 (R)	88
13	6e	7a	8b	RT	77 (R)	55
14	6h	7c	8g	RT	35 (R)	80

^aAll reactions were performed in duplicate: Δee = ±1%, Δconv. = ±5%. The absolute configuration of the product were assigned according to ref. 8. See ESI for experimental details.

^bAfter 7 days.