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. 2015 Oct 28;7(2):945–950. doi: 10.1039/c5sc02992a

Table 1. Electronic properties of oligomers. All potentials are referred to NHE14.

Erd1/2 a (V) ΔErdp a (mV) Eoxp c (V) ErdDFT (V) EoxDFT (V) Eoxp – Erd1/2 Eoptg d (eV)
1a –2.171 b 71 b +2.111 –2.46 1.89 4.282 3.65
2 –1.596 73 +2.119 –1.57 1.71 3.715 3.24
3 –1.296 61 +2.113 –1.32 1.70 3.409 3.16

aQuasi-reversible first half-wave reduction potential.

bMeasured in DMSO.

cFirst irreversible oxidation wave.

d E opt g values were estimated from the start of the absorption spectra.