Table 1. Electronic properties of oligomers. All potentials are referred to NHE14.
| Erd1/2 a (V) | ΔErdp a (mV) | Eoxp c (V) | ErdDFT (V) | EoxDFT (V) | Eoxp – Erd1/2 | Eoptg d (eV) | |
| 1a | –2.171 b | 71 b | +2.111 | –2.46 | 1.89 | 4.282 | 3.65 |
| 2 | –1.596 | 73 | +2.119 | –1.57 | 1.71 | 3.715 | 3.24 |
| 3 | –1.296 | 61 | +2.113 | –1.32 | 1.70 | 3.409 | 3.16 |
aQuasi-reversible first half-wave reduction potential.
bMeasured in DMSO.
cFirst irreversible oxidation wave.
d E opt g values were estimated from the start of the absorption spectra.