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. Author manuscript; available in PMC: 2019 May 25.
Published in final edited form as: J Chromatogr A. 2018 Mar 23;1551:52–58. doi: 10.1016/j.chroma.2018.03.047

Table 1.

A) Reference perfluoro-ether carboxylic acids included in the PFECA standard mixture and B) emerging perfluorinated ether species lacking analytical standards.

A) Perfluorinated Ether Standards
Compound Name CAS Formula Structure
Perfluoro(4-oxapentanoic acid) (“Surrogate 1”) 863090–89-5 C5HF9O3 graphic file with name nihms962147t1.jpg
Perfluoro(3,6-dioxaheptanoic acid) (“Surrogate 2”) 151772–58-6 C5HF9O4 graphic file with name nihms962147t2.jpg
Perfluoro(3-oxabutanoic acid) (“Surrogate 3”) 377–73-1 C4HF7O3 graphic file with name nihms962147t3.jpg
Perfluro(5-oxa-6-dimethylhexanoic) acid (“Surrogate 4”) 801212–59-9 C7HF13O3 graphic file with name nihms962147t4.jpg
Perfluoro(2-methyl-3-oxahexanoic) acid (“HFPO-DA”) 13252–13-6 C6HF11O3 graphic file with name nihms962147t5.jpg

B) Emerging Compounds

Compound Name CAS Formula Structure
Perfluoro-methoxyacetic acid (PFMOAA) 674–13-5 C3HF5O3 graphic file with name nihms962147t6.jpg
Perfluoro-3,5-dioxahexanoic acid (PFO2HxA) 39492–88-1 C4HF7O4 graphic file with name nihms962147t7.jpg
Perfluoro-3,5,7-trioxaoctanoic acid (PFO3OA) 39492–89-2 C5HF9O5 graphic file with name nihms962147t8.jpg