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Thiol and vinyl functionalized monomers, photobase generator NPPOC-TMG, and radical initiator (DMPA) utilized in this study. DMPA, 2,2-dimethoxy-2-phenylacetophenone; DVS, divinyl sulfone; NPPOC-TMG, 2-(2-nitrophenyl)-propyloxycarbonyl-1,1,3,3-tetramethylguanidine; PETMP, pentaerythritol tetra(3-mercaptopropionate); SR368, tris(2-hydroxyethyl)isocyanurate triacrylate; SiTSH, silane thiol.
