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. 2018 May 18;9:1989. doi: 10.1038/s41467-018-04351-0

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© The Author(s) 2018

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 4 — Complete TR-XAS data measured for [Ru(bpy)₂(pyESO)]²⁺ and global fit results. Measured TR-XAS data (scattered) is overlaid with the least-square fit to the kinetic model described in the text (solid lines). a, b Differential absorption spectra at several fixed time-delays at the Ru L₃-edge (a) and S K-edge (b). Vertical lines indicate the energies monitored as a function of time-delay. c, d Time-delay scans at several Ru L₃-edge (c) and S K-edge (d) fixed energies