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. Author manuscript; available in PMC: 2019 Mar 16.
Published in final edited form as: Org Lett. 2018 Mar 5;20(6):1621–1625. doi: 10.1021/acs.orglett.8b00364

Scheme 3. Breadth of olefin coupling partnersa.

Scheme 3

aReactions were performed on a 0.1 mmol scale and were quenched by exposure to air. Isolated yield of a mixture of trans and cis diastereomers. Diastereomeric ratios determined by 1H NMR, enantiomeric ratios determined by CSP-HPLC (254 nm, uncorrected). Average of 2 separate experiments. Ar = 4-CF3Ph. c10 mol % catalyst. dDiastereomeric ratio reported after purification, crude dr 80:20 (trans:cis)