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. Author manuscript; available in PMC: 2018 May 22.
Published in final edited form as: Chem Rev. 2017 Jan 19;117(3):2059–2107. doi: 10.1021/acs.chemrev.6b00636

Figure 60.

Figure 60

(top) X-ray crystal structures of the (1,2-peroxo)dicopper complexes 79 and 80 and (bottom) orthogonal molecular orbitals in 80 that give rise to its S = 1 ground state. Reprinted with permission from ref 38 (top) and ref 354 (bottom). Copyright 2015 Wiley-VCH.