. Author manuscript; available in PMC: 2018 May 22.

Published in final edited form as: Chem Rev. 2017 Jan 19;117(3):2059–2107. doi: 10.1021/acs.chemrev.6b00636

Table 8.

Properties of (1,1-hydroperoxo)dicopper Complexes

ligand	solvent	UV–vis	Raman (exp, cm⁻¹)		ref

		λ_max (nm) (ε, M⁻¹cm⁻¹)	ν(O–O) (Δ¹⁸O)	ν(Cu–O) (Δ¹⁸O)
L54	EtCN	407 (2700), 488 (1600), 622 (600)	870 (50)	–	355
L40f	MeCN	356 (6300), 580 (240), 664 (sh ~190)	868 (45)	572 (16)	357
L40e	MeCN	341 (~7000), 581 (~170), 770 (sh ~80)	883 (50)	562 (23)	357
L58b	MeCN	342 (8600), 444 (850), 610 (400)	–	–	358
L65b	MeCN	416 (5700), 373 (3300)	860 (46)	–	359
L53	acetone	370 (3700), 650 (300)	881 (49)	–	356