Table 2.
Comparison of the catalytic activities between 1a and [{Pt(en)(H2O)}2(μ-pz)]4+ [35] and 3a and [{Pt(en)(H2O)}2(μ-pydz)]4+ [44] complexes in the hydrolysis of Ac–L–Met–Gly dipeptide.
| Platinum(II) complex | Hydrolyzed Met-Gly amide bond (%) | ||
|---|---|---|---|
| 2 h | 12 h | 24 h | |
| [{Pt(en)(H2O)}2(μ-qx)]4+ (1a) | 35 | 52 | 60 |
| [{Pt(en)(H2O)}2(μ-pz)]4+ | 60 | 85 | 88 |
| [{Pt(en)(H2O)}2(μ-phtz)]4+(3a) | 8 | 28 | 41 |
| [{Pt(en)(H2O)}2(μ-pydz)]4+ | 12 | 36 | 54 |