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. 2015 Dec 8;7(3):2037–2050. doi: 10.1039/c5sc03494a

Table 2. Cation exchange a (%) for [(Fp–L)x(TEA)3–x][In3(BTC)4] under various conditions determined by ICP-OES b (x = 3 corresponds to 100%).

[TEA]3[In3(BTC)4] + x[Fp–L][BF4] → [(Fp–L)x(TEA)3–x][In3(BTC)4] + x[TEA][BF4]
24 h (soaking, 25 °C) 24 h (soaking, 5 °C) 48 h (soaking, 5 °C)
23% (x = 0.69) 15% (x = 0.45) 20% (x = 0.60)

aConditions: 0.02 M solution of [Fp–THF][BF4] in dry acetone, initial ratio [(Fp–L)+]/[TEA] = 1/1.

bDigestion in diluted HNO3 (1/10 v/v).