Table 2. Cation exchange a (%) for [(Fp–L)x(TEA)3–x][In3(BTC)4] under various conditions determined by ICP-OES b (x = 3 corresponds to 100%).
| [TEA]3[In3(BTC)4] + x[Fp–L][BF4] → [(Fp–L)x(TEA)3–x][In3(BTC)4] + x[TEA][BF4] | ||
| 24 h (soaking, 25 °C) | 24 h (soaking, 5 °C) | 48 h (soaking, 5 °C) |
| 23% (x = 0.69) | 15% (x = 0.45) | 20% (x = 0.60) |
aConditions: 0.02 M solution of [Fp–THF][BF4] in dry acetone, initial ratio [(Fp–L)+]/[TEA] = 1/1.
bDigestion in diluted HNO3 (1/10 v/v).