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. Author manuscript; available in PMC: 2018 May 25.
Published in final edited form as: J Am Chem Soc. 2018 Apr 27;140(18):5895–5898. doi: 10.1021/jacs.8b02751

Table 2.

Scope of allylic aryl enol ethers.

graphic file with name nihms968190f5.jpg

Yields are reported as an average of two parallel experiments. Enantioselectivity determined by SFC equipped with a chiral column. Reaction performed on 0.25 mmol scale. Absolute configuration determined to be (S) for a synthetic derivative of 5z (see Supporting Information) arising from the (E)-alkene. All other products were assigned by analogy.

a

THF and L2 ligand used instead of DMF and L1 ligand.