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. 2018 Apr 24;9(20):4650–4661. doi: 10.1039/c8sc00443a

Table 5. Metal foil-catalyzed cycloaddition of enynes with methyl phenyldiazoacetate a .

Inline graphic
Entry Enyne Ag foil
Cu foil
Product Yield b (%) Product Yield b (%)
1 graphic file with name c8sc00443a-u7.jpg graphic file with name c8sc00443a-u8.jpg 68 graphic file with name c8sc00443a-u9.jpg 55
2 graphic file with name c8sc00443a-u10.jpg graphic file with name c8sc00443a-u11.jpg 74 graphic file with name c8sc00443a-u12.jpg 80
3 graphic file with name c8sc00443a-u13.jpg graphic file with name c8sc00443a-u14.jpg 0 c graphic file with name c8sc00443a-u15.jpg 86
4 graphic file with name c8sc00443a-u16.jpg graphic file with name c8sc00443a-u17.jpg 74 graphic file with name c8sc00443a-u18.jpg 85

aReaction conditions: diazoacetate (1.00 eq.), enyne (5.00 eq.) and copper foil added to a SPEX 8000M mixer/mill (18 Hz) for 16 h.

bGC yield.

cRecovered starting materials.