Table 1.
Optimized MS parameters for PMX53 and PMX205.
| Analyte | ID | Q1 (Da) | Q3 (Da) | Dwell time (msec) | DP (V) | EP (V) | CEP (V) | CE (V) | CXP (V) |
|---|---|---|---|---|---|---|---|---|---|
| PMX53 | Fragment 1 (Quantifier) | 448.6 | 120.2 | 150 | 46 | 4 | 20 | 53 | 4 |
| Fragment 2 (Qualifier 1) | 448.6 | 70.0 | 150 | 46 | 4 | 20 | 73 | 14 | |
| Fragment 3 (Qualifier 2) | 448.6 | 162.1 | 150 | 30 | 7 | 20 | 29 | 4 | |
| PMX205 | Fragment 1 (Quantifier) | 420.2 | 70.0 | 150 | 30 | 4 | 20 | 53 | 6 |
| Fragment 2 (Qualifier 1) | 420.2 | 105.2 | 150 | 26 | 2.5 | 20 | 55 | 12 | |
| Fragment 3 (Qualifier 2) | 420.2 | 126.0 | 150 | 26 | 7 | 20 | 53 | 4 |
Q1, mass of analyte in (+2) ionization state; Q3, fragment mass; DP, declustring potential; EP, entrance potential; CEP, collision cell entrance potential; CE, collision energy; CXP, collision cell exit potential.