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. Author manuscript; available in PMC: 2019 Apr 4.
Published in final edited form as: J Am Chem Soc. 2018 Mar 23;140(13):4503–4507. doi: 10.1021/jacs.8b01726

Table 2.

Ni-Catalyzed Enantioselective Dearomative trans-1,2-Carboaminationa

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a

All reactions were run on 0.5 mmol scale under the standard conditions. For 2p, 1.0 mmol of naphthalene (2.0 equiv) was used. Reported yields are of isolated products and er was determined by HPLC analysis.

b

Run on 3.0 g (26.5 mmol) scale.

c

Run on 6.0 g (53.1 mmol) scale.