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. Author manuscript; available in PMC: 2019 May 7.
Published in final edited form as: Inorg Chem. 2018 Apr 10;57(9):5449–5462. doi: 10.1021/acs.inorgchem.8b00419

Figure 7.

Figure 7

Comparison of experimental and RAS-theoretical x-ray absorption spectra in transmission mode (XAS) and in partial fluorescence yield mode (PFY-XAS) for MnII(acac)2 and MnIII(acac)3 in solution samples. Experimental and RAS calculated PFY-XAS spectra (black) are copied from ref. 13. All spectra are normalized to their peak intensity. The transmission XAS spectra in (A) and (B) were taken from Fig. 3A, those in (C) and (D) from Fig. 3B. Notably, the energy position of the features is conserved for both detection modes.