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. Author manuscript; available in PMC: 2018 May 29.
Published in final edited form as: J Am Chem Soc. 2018 Apr 11;140(16):5544–5559. doi: 10.1021/jacs.8b01822

Figure 1.

Figure 1

NRVS spectra of BZDO. The Rieske center is loaded with 57Fe in all spectra. Black: NRVS of the Rieske center (apo BZDO, catalytic site not loaded with 57Fe). Red: BZDOOX (catalytic site loaded with 57Fe). Blue: BZDOp generated with H2 16O2 (catalytic site loaded with 57Fe). Inset: NRVS of BZDOp generated with H2 16O2 (blue solid line) and H2 18O2 (blue dashed line) in the region between 485 and 520 cm−1 showing a low-intensity isotope-sensitive feature. These data were collected with a 10× longer measurement time between 460 and 540 cm−1 than the spectrum shown in blue at the bottom of this figure (see the Methods). Error bars (gray) are calculated based on the number of counts in the raw spectrum and were propagated upon baseline subtraction (see Figure S2 for the PVDOS spectra for 16O and 18O BZDOp between 460 and 540 cm−1).