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. Author manuscript; available in PMC: 2018 May 29.
Published in final edited form as: J Am Chem Soc. 2018 Apr 11;140(16):5544–5559. doi: 10.1021/jacs.8b01822

Scheme 1. Two Possible Reaction Mechanisms for BZDOp Involving an O–O Cleavage Prior to Reaction with Substrate (1) or Direct Attack on the Substrate Concerted with O–O Cleavage (2)a.

Scheme 1

aThe Rieske center remains oxidized throughout and does not participate in the shunt reaction.