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. 2018 Apr 30;20(21):14525–14536. doi: 10.1039/c8cp02244e

Table 6. Structural information about the hydrated and dmf, dma, dmso, methanol and ethanol solvated alkali metal, alkaline earth metal, lanthanum(iii), gadolinium(iii) and lutetium(iii) ions in solution given as coordination number/M–O bond distance (Å), ionic radius (Å), and charge density (charge per ionic volume in Å³, based on ionic radius). Data in italics are estimated structure parameters based on the size of the solvent molecule.

	Na⁺	K⁺	Rb⁺	Cs⁺	Ref.
Water	6/2.43/1.09/0.184	7/2.81/1.47/0.075	8/2.98/1.64/0.054	8/3.08/1.74/0.045	63 and 69
dmf	6/2.42/1.09/0.184	7/2.80/1.47/0.075	8/2.97/1.64/0.054	8/3.07/1.74/0.045
dma	6/2.42/1.09/0.184	7/2.80/1.47/0.075	8/2.97/1.64/0.054	8/3.07/1.74/0.045
dmso	6/2.43/1.09/0.184	7/2.79/1.45/0.078	8/2.98/1.64/0.054	8/3.06/1.72/0.047	63 and 69
Methanol	6/2.43/1.09/0.184	7/2.81/1.47/0.075	8/2.98/1.64/0.054	8/3.08/1.74/0.045
Ethanol	6/2.43/1.09/0.184	7/2.81/1.47/0.075	8/2.98/1.64/0.054	8/3.08/1.74/0.045

	Mg²⁺	Ca²⁺	Sr²⁺	Ba²⁺	Ref.
Water	6/2.07/0.73/1.227	8/2.48/1.14/0.322	8/2.62/1.28/0.228	8/2.79/1.45/0.157	49, 64, 70 and 71 & Table S1 (ESI)
dmf	6/2.057/0.725/1.253	6/2.31/0.97/0.523	6.5/2.51/1.12/0.298	7.4/2.73/1.39/0.178	Tables 4, 5 & Table S2 (ESI)
dma	6/2.06/0.73/1.227	7/2.31/0.97/0.523	6.4/2.49/1.17/0.314	7/32.71/1.37/0.186	Tables 4, 5 & Table S2 (ESI)
dmso	6/2.07/0.73/1.227	7/2.36/1.02/0.450	6.9/2.54/1.20/0.276	7.7/2.76/1.42/0.167	31,49 & Table S3 (ESI)
Methanol	6/2.07/0.73/1.227	8/2.48/1.14/0.322	8/2.62/1.28/0.228	8/2.79/1.45/0.157	Table S3 (ESI)
Ethanol	6/2.07/0.73/1.227	8/2.48/1.14/0.322	8/2.62/1.28/0.228	8/2.79/1.45/0.157	Table S3 (ESI)

	Mn²⁺	Co²⁺	Ni²⁺	Zn²⁺	Ref.
Water	6/2.175/0.835/0.820	6/2.09/0.75/1.132	6/2.055/0.715/1.306	6/2.089/0.75/1.123	72–75 & Table S1 (ESI)
dmf	6/2.17/0.84/0.806	6/2.085/0.755/1.109	6/2.045/0.715/1.306	6/2.104/0.765/1.066	Table S3 (ESI)
dma	6/2.20/0.86/0.751	6/2.08/0.74/1.178	6/2.066/0.725/1.253	6/2.08/0.74/1.178	Table S3 (ESI)
dmso	6/2.17/0.83/0.835	6/2.096/0.755/1.109	6/2.068/0.73/1.227	6/2.11/0.77/1.046	73, 76 and 77 & Table S3 (ESI)
Methanol	6/2.164/0.825/0.850	6/2.09/0.75/1.132	6/2.061/0.72/1.279	6/2.086/0.745/1.253	78 & Table S3 (ESI)
Ethanol	6/2.20/0.86/0.751	6/2.09/0.75/1.132	6/2.055/0.715/1.306	6/2.079/0.74/1.178	Table S3 (ESI)

	La³⁺	Gd³⁺	Lu³⁺	Ref.
Water	9/2.56/1.22/0.394	9/2.41/1.07/0.585	8.2/2.31/0.97/0.785	65 & Table 1
dmf	9/2.55/1.22/0.394	8/2.38/1.05/0.619	8/2.30/0.97/0.785	48 & Table S3 (ESI)
dma	8/2.50/1.16/0.459	8/2.39/1.05/0.619	8/2.23/0.89/1.016	48 & Table S3 (ESI)
dmso	8/2.49/1.15/0.471	8/2.38/1.04/0.637	8/2.30/0.96/0.601	67 & Table S3 (ESI)
Methanol	9/2.56/1.22/0.394	8/2.39/1.05/0.619	8/2.29/0.95/0.835	Table S3 (ESI)
Ethanol	9/2.56/1.22/0.394	8/2.39/1.05/0.619	8/2.29/0.95/0.835	Table S3 (ESI)

	Al³⁺	Cr³⁺	Fe³⁺	Ref.
Water	6/1.90/0.56/4.08	6/1.96/0.62/3.01	6/2.00/0.66/2.49	79–81 & Table S3 (ESI)
dmso	6/1.90/0.56/4.08		6/2.00/0.66/2.49	82 and Table S3 (ESI)