Table 3.
Extraction efficacies of the synthesized ILs in spiked synthetic as well as natural water feed solutions for an extraction time of 1 h, n = 3.
| Extraction efficacy (%) | |||||
|---|---|---|---|---|---|
| Sample | IL | Ag | Cd | Cu | Pb |
| Pure water | [P66614][HNA] | 47.1 ± 2.0 | 35.0 ± 0.8 | 58.8 ± 3.5 | 75.9 ± 7.5 |
| [P1888][HNA] | 16.1 ± 0.9 | 41.1 ± 5.4 | 73.2 ± 2.3 | 53.8 ± 4.2 | |
| [N1888][HNA] | 14.1 ± 0.9 | 41.9 ± 4.7 | 91.6 ± 0.7 | 74.4 ± 1.2 | |
| [P66614][HNA] | 63.3 ± 1.7 | 80.9 ± 4.8 | 60.9 ± 2.4 | 54.2 ± 9.2 | |
| Water-NaCl | [P1888][HNA] | 24.0 ± 1.6 | 34.8 ± 3.9 | 67.7 ± 1.9 | 43.9 ± 2.8 |
| [N1888][HNA] | 37.9 ± 3.3 | 41.9 ± 7.4 | 51.5 ± 5.7 | 40.1 ± 3.7 | |
| [P66614][HNA] | 41.6 ± 4.8 | 34.4 ± 5.6 | 29.9 ± 3.9 | 35.7 ± 5.8 | |
| Water-HS | [P1888][HNA] | 21.3 ± 0.6 | 33.0 ± 1.0 | 22.1 ± 0.5 | 21.9 ± 4.4 |
| [N1888][HNA] | 13.2 ± 4.1 | 22.8 ± 3.3 | 20.5 ± 1.6 | 13.9 ± 7.2 | |
| [P66614][HNA] | 60.8 ± 1.0 | 82.4 ± 1.5 | 52.3 ± 0.7 | 31.3 ± 10.8 | |
| Water-HS-NaCl | [P1888][HNA] | 32.6 ± 1.7 | 23.1 ± 3.7 | 24.9 ± 3.0 | 23.4 ± 0.9 |
| [N1888][HNA] | 8.4 ± 3.7 | 38.9 ± 5.3 | 21.7 ± 7.5 | 22.7 ± 6.3 | |
| [P66614][HNA] | 81.1 ± 1.5 | 73.5 ± 6.8 | 81.3 ± 6.8 | 75.3 ± 1.4 | |
| Drinking water | [P1888][HNA] | 73.0 ± 3.8 | 44.0 ± 5.8 | 71.7 ± 2.3 | 57.7 ± 4.2 |
| [N1888][HNA] | 78.4 ± 8.4 | 45.2 ± 5.1 | 91.4 ± 2.3 | 63.6 ± 6.9 | |
| [P66614][HNA] | 1.9 ± 1.6 | 64.4 ± 2.0 | 51.4 ± 0.0 | 36.1 ± 2.4 | |
| WWTP effluent | [P1888][HNA] | 0.8 ± 0.5 | 36.7 ± 1.8 | 44.6 ± 1.4 | 20.7 ± 0.0 |
| [N1888][HNA] | 3.4 ± 0.5 | 20.3 ± 6.3 | 42.2 ± 8.9 | 6.9 ± 0.0 | |
| [P66614][HNA] | 62.0 ± 0.9 | 73.9 ± 0.5 | 57.4 ± 4.6 | 39.4 ± 5.3 | |
| Seawater | [P1888][HNA] | 30.7 ± 5.1 | 56.6 ± 4.6 | 63.5 ± 6.6 | 28.3 ± 2.1 |
| [N1888][HNA] | 29.0 ± 2.8 | 52.0 ± 4.0 | 48.1 ± 5.9 | 19.3 ± 2.1 | |
| [P66614][HNA] | 56.9 ± 2.3 | 76.0 ± 4.4 | 51.8 ± 9.9 | 29.5 ± 4.0 | |
| Hypersaline water | [P1888][HNA] | 19.6 ± 5.0 | 44.0 ± 6.0 | 31.3 ± 5.9 | 14.0 ± 2.0 |
| [N1888][HNA] | 7.1 ± 0.0 | 38.3 ± 3.4 | 29.4 ± 3.3 | 15.4 ± 2.0 | |