Table 1.
Compd. | R1 | R2 | Compd. | R1 | R2 |
---|---|---|---|---|---|
1 | H | butyryl | 17 | butyryl | |
2 | H | isobutyryl | 18 | acetyl | |
3 | H | pivaloyl | 19 | acetyl | |
4 | butyryl | 20 | acetyl | ||
5 | butyryl | 21 | acetyl | ||
6 | acetyl | 22 | butyryl | ||
7 | acetyl | 23 | butyryl | ||
8 | propionyl | 24 | butyryl | ||
9 | isobutyryl | 25 | butyryl | ||
10 | butyryl | 26 | butyryl | ||
11 | heptanoyl | 27 | butyryl | ||
12 | benzoyl | 28 | butyryl | ||
13 | butyryl | 29 | butyryl | ||
14 | butyryl | 30 | acetyl | ||
15 | acetyl | 31 | butyryl | ||
16 | isobutyryl | 32 | H | acetyl |
A series of 4′-substituted bis(alkanoyloxymethyl) 2,2′:6′,2″-terpyridine-6,6″-dicarboxylate derivatives were designed and synthesized as described in Supporting Information. BATDA is shown as compound 32.