Skip to main content
. 2015 Dec 3;7(3):2229–2238. doi: 10.1039/c5sc03905c

Table 1. Regioselectivity with different metals on N-methyl-benzanilides.

Inline graphic
Entry Catalyst 2a yield a (%) 2b yield a (%)
1 FeBr3 <5 <5
2 Fe(OAc)2 <5 <5
3 Co(OAc)2 <5 <5
4 CoF3 <5 <5
5 Bis(1,5-cyclooctadiene)nickel <5 <5
6 Bis(triphenylphosphine)nickel dichloride <5 <5
7 CuI <5 <5
8 [μ-Bis(diphenylphosphino)methane]Au2Cl2 <5 <5
9 AuCl <5 <5
10 Mn(OAc)2 <5 <5
11 NbCl5 <5 <5
12 (1,5-Cyclooctadiene)(methoxy)iridium <5 <5
13 Ce(SO4)2·4H2O <5 <5
14 Rh2(TFA)4 <5 43
15 [(C6H5)3P]3RhCl <5 8
16 [Cp*RhCl2]2 <5 <5
17 Rh2(OAc)4 <5 37
18 [Ru(p-cymene)Cl 2 ] 2 <5 93 b
19 [(C6H5)3P]3Ru(CO)(Cl)H <5 73
20 [(C6H5)3P]3RuCl2 <5 60
21 c Pd(OAc) 2 70 b <5
22 c Pd(acac)2 67 <5
23 c Pd(TFA)2 57 <5

aConversion ratio.

bIsolated yield.

c0.5 h.