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. Author manuscript; available in PMC: 2018 Jun 1.
Published in final edited form as: Chem Rev. 2017 Nov 20;118(5):2593–2635. doi: 10.1021/acs.chemrev.7b00421

Figure 28.

Figure 28

Renderings of Cu/O2 complexes reported to date with bond lengths given in Angstroms. (Left) Cu/O2 species reported by Li et al. in chain A of NcLPMO9D (PDB ID 4EIR) (A) and in chain A of NcLPMO9M (PDB ID 4EIS) (B). (C and D) Copper active site for NcLPMO9D treated with ascorbate and exposed to atmospheric O2 (PDB ID 5TKH). O–O electron density is oriented in an end-on geometry. In C the Cu–O distance is 1.9 Å. (E and F) Copper active site of JdLPMO10A.