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. 2018 Mar 28;25(16):16037–16049. doi: 10.1007/s11356-018-1796-6

Table 3.

Physical–chemical properties of EHMC and its transformation products

No. Compound References Molecular formula Mol wt [g mol−1] MP [°C] BP [°C] S [mg L−1] VP [mmHg] BCF Log KOW = log P Log KOA Log KOC Log KAW Henry’s LC [mol dm−3 atm−1] Half-life air [h] Half-life water [h] Half-life soil [h] POV [days] LRTP [km]
1 E-EHMC – C18H26O3 290.41 99.87 360.54 0.1548 1.38·10−5 667.6 5.80 9.938 4.089 − 4.138 29.4 4.17 360 720 43.26 90.80
2 EHA 1, 2 C8H18O1 130.23 − 70 184.6 880 0.185 25.33 2.73 5.69 1.415 − 2.965 44.9 19.4 208 416 23.02 385.20
3 4MCA 1, 3 C10H10O3 178.19 96 317 712 1.6·10−4 3.162 2.68 10.19 1.536 − 7.505 19,300 5.02 360 720 41.41 37.37
4 4MBA 1, 2 C8H8O2 136.15 0 248 4290 0.0303 4.521 1.76 6.25 1.367 − 4.489 54,600 10.4 360 720 33.49 204.03
5 4MP 1 C7H8O2 124.14 57 243 40,000 0.0083 3.285 1.58 7.447 2.28 − 5.867 12,200 8.62 360 720 34.36 150.24
6 1Cl4MB 4 C7H7CIO 142.59 ≤ 18 197.5 237 0.409 27.58 2.78 4.796 2.280 − 2.016 4.46 36.1 900 1.8e + 003 40.73 740.0
7 1.3DCl2MB 4 C7H6Cl2O 177.03 < 25 215.67 140 0.164 52.22 3.14 5.825 2.508 − 2.145 3.1 96.4 900 1.8e + 003 67.67 1912.83
8 2-EHCA 4 C10H19ClO2 192.69 − 8.26 207 48.86 0.168 236.2 3.50 3.655 2.632 − 1.736 2.03 24.9 360 720 33.86 514.10
9 3Cl4MBA 1 C8H7ClO2 170.60 42.61 250.91 508.2 0.0176 14.98 2.44 7.058 1.518 − 4.618 130.0 13 900 1.8e + 003 87.91 250.74
10 Z-EHMC 1, 5 C18H26O3 290.41 99.87 360.54 0.1548 1.38·10−5 667.6 5.80 9.938 4.089 − 4.138 29.4 4.17 360 720 43.26 90.80
11 EHMCCl 6, 7 C18H25ClO3 324.85 128.01 386.23 0.01943 1.68·10−6 661.4 6.45 10.777 4.344 − 4.268 33.0 4.63 900 1.8e + 003 108.13 133.19
12 EHMCCl2 4, 6, 7 C18H24Cl2O3 359.30 149.44 404.93 0.00437 3.42·10−7 1215 7.16 11.559 4.562 − 4.399 25.6 5.65 900 1.8e + 003 108.15 410.66
13 2.4 DClP 4 C6H4Cl2O 163.0 45.0 210.0 4500 0.09 18.04 3.06 7.108 2.856 − 3.756 43.7 242 900 1.8e + 003 99.62 2473.19
14 2.6DCl1.4BQ 4 C6H2Cl2O2 176.99 123 268.4 5056 0.00189 1.771 1.23 8.818 1.0 − 7.588 11,500 52 900 1.8e + 003 70.56 93.35
15 1.2.4TCl3MB 4 C7H5Cl3O 211.45 45 227 29.73 0.056 126.7 3.64 5.569 2.726 − 1.929 1.89 121 1.44e + 003 2.88e + 003 113.33 2433.26
16 2.4.6TClP 4 C6H3Cl3O 197.45 69 246 800 0.008 55.12 3.69 7.663 3.074 − 3.973 385 423 1.44e + 003 2.88e + 003 166.36 2977.4
17 3.5DCl2HAcP 4 C8H6Cl2O2 205.04 90.66 299.08 258 1.6·10−4 3.713 3.26 7.8 2.31 − 4.540 5940 492 900 1.8e + 003 103.71 2663.03
18 3Cl4MCA 1 C10H9ClO3 212.63 109.81 337.48 382.6 3.75·10−5 3.162 2.80 10.435 1.75 − 7.635 36,500 6.98 360 720 41.81 37.37
19 3.5DCl4MCA 1 C10H8Cl2O3 247.08 128.70 356.76 70.28 8.38·10−6 3.162 3.44 11.205 1.973 − 7.765 25,800 8.1 900 1.8e + 003 105.91 93.34
20 3.5DCl4MBA 1 C8H6Cl2O2 205.04 63.98 277.85 96.55 0.00271 46.95 3.08 7.829 1.803 − 4.749 132 14.2 900 1.8e + 003 101.28 270.76
21 3Cl4MP 1 C7H7ClO2 158.59 51.00 241.49 3238 0.0103 10.55 2.24 8.238 2.499 − 5.998 151 12.1 900 1.8e + 003 87.81 187.43
22 2.5DCl4MP 1 C7H6Cl2O2 193.03 67.83 269.20 623.1 0.00379 13.17 2.88 9.008 2.717 − 6.128 1640 37.2 900 1.8e + 003 100.89 330.32
23 TP199 3 C9H10O5 198.18 152.73 371.83 9287 1.35·10−7 3.162 0.80 18.901 3.458 − 18.105 2.64·108 1.04 360 720 31.72 37.37
24 TP307e 3 C18H26O4 306.41 141.55 395.38 1.221 1.54·10−7 2500 5.32 13.441 4.308 − 8.121 19,700 1.06 360 720 43.27 846.70
25 TP307f 3 C18H26O4 306.41 141.55 395.38 0.5314 1.54·10−7 1588 5.07 13.191 4.308 − 8.121 8560 3.75 360 720 43.26 634.76
26 TP305a 3 C18H26O4 304.39 124.33 383.31 7.226 2.17·10−6 154.6 3.75 11.306 3.031 − 7.556 8310 4.09 900 1.8e + 003 107.01 93.33
27 TP305b 3 C18H26O4 304.39 129.46 389.96 2.402 1.31·10−6 417.5 4.31 11.609 3.155 − 7.299 4580 2.86 900 1.8e + 003 100.75 93.35
28 TP305c 3 C18H26O4 304.39 90.85 348.94 2.186 3.24·10−5 454.6 4.36 9.312 3.217 − 4.952 168 4.51 900 1.8e + 003 107.71 92.91
29 TP305d 3 C18H26O4 304.39 129.46 389.96 2.402 1.31·10−6 417.5 4.31 11.609 3.155 − 7.299 4580 3.02 900 1.8e + 003 107.82 101.10
30 TP305e 3 C18H26O4 304.39 124.33 383.11 7.226 2.17·10−6 154.6 3.75 11.306 3.05 − 7.556 8310 3.82 900 1.8e + 003 107.01 93.34
31 TP305f 3 C18H26O4 304.39 124.33 383.31 7.226 2.17·10−6 154.6 3.75 11.306 3.06 − 8.121 8310 3.75 360 720 43.09 44.32
32 TP469a 3 C28H36O6 468.60 246.19 571.92 0.012 1.58·10−12 56.23 6.27 19.064 3.817 − 12.794 4.23·1010 2.93 900 1.8e + 003 108.14 2373.53
33 TP469b 3 C28H36O6 468.60 246.19 571.92 0.012 1.58·10−12 56.23 6.27 19.064 3.817 − 12.794 4.23·1010 2.93 900 1.8e + 003 108.14 2373.53
34 DIAMC 8 C30H40O6 496.65 243.43 566.01 0.009 2.42·10−12 5410 5.76 17.679 3.644 − 11.919 5.76·105 2.68 900 1.8e + 003 108.123 1718.79
35 TP581b 2, 3, 8 C36H52O6 580.81 269.42 621.64 1.057·10−5 4.12·10−14 15.03 8.56 19.742 5.167 − 11.182 3.36·105 2.18 1.44e + 003 2.88e + 003 173.03 2857.92

1 Gackowska et al. (2014), 2 MacManus-Spencer et al. (2011), 3 Jentzsch et al. (2016), 4 Gackowska et al. (2016), 5 Serpone et al. (2002), 6 Nakajima et al. (2009), 7 Santos et al. (2013), 8 Rodil et al. (2009)