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. Author manuscript; available in PMC: 2018 Dec 5.
Published in final edited form as: Inorg Chem. 2018 Feb 21;57(5):2333–2350. doi: 10.1021/acs.inorgchem.7b02912

Figure 8.

Figure 8

A. Redox potentials of [B12(OR)12] clusters plotted vs Hammett constants (top/blue = 1- to 0, bottom/red = 2- to 1-). B. Single crystal X-ray structure of cluster [e]1−. C. UV-vis spectra and photos of the air-stable radical cluster [e]1− (red line) and the dianionic cluster [e]2− (blue dashed line). D. EPR spectrum of the radical cluster [e]1−. These highlight the tunable nature of the perfunctionalized clusters.10,44,95