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. Author manuscript; available in PMC: 2018 Jun 4.
Published in final edited form as: Inorg Chem. 2016 Jun 14;55(13):6364–6375. doi: 10.1021/acs.inorgchem.6b01034

Figure 5.

Figure 5

Models of possible O2 intermediates in the non-coupled binuclear CuM site in PHM. (A) Two-electron reduced CuM(II)OOH. (B) One-electron reduced side-on superoxide CuM(II). Left: Geometry optimized model. Center: FMO. Right: resonance Raman data on the model complex.