Table 1.
Recently reported biphasic hydrophobic IL-based reaction systems in biocatalysis
| Entry | Investigated biphasic reaction systems | Biocatalytic reaction system | Reference |
|---|---|---|---|
| Classical biphasic reaction system | |||
| 1 | [BMIM][PF6]/buffer | β-Glucuronidase (PGUS-E) from Penicillium purpurogenum Li-3; immobilized on zinc oxide nanoparticles | (Kaleem et al. 2017) |
| 2 | [BMIM][NTf2]/buffer | Commercial alcohol dehydrogenase, expressed in E. coli and alanine aminotransferase isolated from porcine heart | (Voges et al. 2017) |
| 3 | [HPYR][NTF]/buffer | Whole cells of Escherichia coli overexpressing a glucosyltransferase from Vitis vinifera | (Schmideder et al. 2016) |
| 4 | Various ILs/buffer | Acetobacter pasteurianus Gim1.158 whole cells | (Xu et al. 2016) |
| 5 | [BMIM][PF6] and [NTf2]/buffer | Baker’s yeast (BY) and old yellow enzyme (OYE1-3) | (Brenna et al. 2014) |
| 6 | Various ILs/buffer | Rhodotorula glutinis whole cells | (Matsumoto et al. 2014) |
| 7 | Various ILs/buffer | Mung bean epoxide hydrolases, cross-linked enzyme aggregates (CLEAs) | (Yu et al. 2014) |
| 8 | Various ILs/various organic solvents | Various lipases | (Fischer et al. 2013) |
| 9 | [BMPY][NTf2], | Candida antarctica lipase B (CalB) | (Pohar et al. 2012) |
| 10 | Various ILs/buffer | Naringinase from Penicillium decumbens | (Temme et al. 2012) |
| 11 | [BMIM][PF6]/buffer | Immobilized Candida parapsilosis CCTCC M203011 whole cells | (Zhang et al. 2012) |
| 12 | [BMIM][NTf2]/buffer | Escherichia coli whole cells co-expressing yeast reductase YOL151W and Bacillus subtilis glucose dehydrogenase | (Choi et al. 2011) |
| 13 | [HMPL][NTF2]/buffer | Escherichia coli whole cells overexpressing the Lactobacillus brevis alcohol dehydrogenase (ADH) and the Candida boidinii formate dehydrogenase (FDH) | (Dennewald et al. 2011) |
| 14 | [BMIM][PF6]/isoamyl alcohol | Candida antarctica lipase B (CalB) | (Eisenmenger and Reyes-De-Corcuera 2010) |
| 15 | [BMIM][PF6]/buffer | Recombinant β-d-glucuronidase from Escherichia coli BL21 (PGUS-E) | (He et al. 2010) |
| Reaction-induced phase change | |||
| 16 | Various Ammoeng ILs/reactant phase | Various lipases | (Devi et al. 2011) |
| Supported ILs | |||
| 17 | Membrane separator containing [BMIM][NTf2] and [HMIM][PF6] | Biocatalytic electrochemical cell (supported ionic liquid membranes (SILMs)) | (Koók et al. 2017) |
| 18 | [OMIM][BF4]/MTBE as transport phase | Candida antarctica lipase B (CalB) | (Sandig et al. 2015) |
| Influence of IL-based biphasic reaction system | |||
| 19 | [BMIM][PF6]/buffer | Effects of [BMIM][PF6] on Saccharomyces cerevisiae | (Song et al. 2011) |
| 20 | Various ILs/buffer | Escherichia coli K-12 agar diffusion tests and growth inhibition tests | (Wood et al. 2011) |